Complexation of novel diglycolamide functionalized calix[4]arenes: unusual extraction behaviour, transport, and fluorescence studies.

نویسندگان

  • Prasanta K Mohapatra
  • Mudassir Iqbal
  • Dhaval R Raut
  • Willem Verboom
  • Jurriaan Huskens
  • Shrikant V Godbole
چکیده

Three diglycolamide functionalized calix[4]arenes (calix[4]-nDGA) were synthesized and evaluated for their extraction behaviour towards lanthanide/actinide ions. Exceptionally high D(Am) and D(Pu) values indicate these radiotoxic elements can be selectively removed from nuclear waste solutions. Transport and laser induced fluorescence studies indicated strong complexation of the trivalent metal ions with the calix[4]-4DGA ligand.

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عنوان ژورنال:
  • Dalton transactions

دوره 41 2  شماره 

صفحات  -

تاریخ انتشار 2012